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Soil and atmospheric concentrations, dry deposition and soil-air gas exchange of organochlorine pesticides (OCPs) were investigated at an industrial site in Aliaga, Izmir, Turkey. Current-use pesticides, endosulfan and chlorpyrifos, had the highest atmospheric levels in summer and winter. Summertime total (gas + particle) OCP concentrations in air were higher, probably due to increased volatilization at higher temperatures and seasonal local/regional applications of current-use pesticides. Particle deposition fluxes were generally higher in summer than in winter. Overall average dry particle deposition velocity for all the OCPs was 4.9 ± 4.1 cm s−1 (average ± SD). ΣDDXs (sum of p,p′-DDT, p,p′-DDD, and p,p′-DDE) were the most abundant OCPs in Aliaga soils (n = 48), probably due to their heavy historical use and persistence. Calculated fugacity ratios and average net gas fluxes across the soil-air interface indicated volatilization for α-CHL, γ-CHL, heptachlorepoxide, cis-nonachlor, trans-nonachlor, and p,p′-DDT in summer, and for α-CHL, γ-CHL, trans-nonachlor, endosulfan sulfate, and p,p′-DDT in winter. For the remaining OCPs, soil acted as a sink during both seasons. Comparison of the determined fluxes showed that dry particle, gas-phase, and wet deposition are significant OCP input mechanisms to the soil in the study area. 相似文献
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125.
两阶段曝气生物滤池的硝化性能 总被引:2,自引:1,他引:1
曝气生物滤池(BAF)是近年来受到广泛关注的一种新型污水处理技术,具有占地面积少、投资费用低、处理效率高、出水水质好等优点。现已被应用于许多污水处理厂的二级处理、深度处理以及污水的回用。实验以陶粒为填料,自行设计了升流式两阶段BAFs(UBAFs)处理模拟生活污水,考察了反应器运行条件对COD与氨氮去除影响,并探讨了UBAFs反应器内氮流失及同步硝化反硝化情况。结果表明,UBAFs对生活污水处理具有良好的净化效果。在进水COD和氨氮浓度分别为200~363 mg/L和16.8~31.3 mg/L条件下,UBAFs处理出水水质均达到《城市污水再生利用城市杂用水水质》(GB/T 18920-2002)标准,能够满足回用要求。通过采用氮平衡分析方法和借助电子扫描电镜技术,初步认为UBAFs反应器脱氮方式是由于在UBAFs第一阶段局部厌氧环境中以传统方式进行硝化反硝化脱氮,第二阶段是在好氧条件下,异养好氧硝化菌的同步硝化反硝化脱氮。 相似文献
126.
尾矿高浓度排放技术的发展概况及展望 总被引:2,自引:0,他引:2
对于尾矿传统湿排技术来说,不仅坝体的稳定性差,对环境也有极大的影响,然而高浓度排放技术有效地缓解或解决了这些问题。文章从尾矿脱水、料浆输送和尾矿沉积等多方面,介绍了高浓度排放国内外发展情况,如多段式到一段式脱水和脱水设备的发展、泵压输送中泵送设备的类型,以及尾矿沉积中排放口的布置方式等。介绍了边坡角预测理论,主要包括Blight和Bentel边坡角预测模型、Kupper提出的边坡角经验公式,以及Sofra和Boger提出的边坡角经验公式。指出了高浓度排放技术存在的问题,如膏体的定义不清晰、高浓度排放的适用条件、沉积裂缝和边坡角预测模型不精确。最后总结了高浓度排放的发展趋势,如膏体排放模式、排放口的中央式布置和设备选型,如高浓度底流和处理量的脱水设备,以及高压高效率的泵送设备等。 相似文献
127.
M. W. Kress R. Baker S. J. Ursic 《Journal of the American Water Resources Association》1990,26(5):747-756
ABSTRACT: The deposition and chemistry of precipitation were estimated for one year in two forest ecosystems in the South-Central United States. Precipitation, throughfall, litter leachate, and soil leachate were analyzed for a small catchment of pine-hardwoods in southeastern Oklahoma and for a catchment of loblolly pines (Pinus taeda L.) in northern Mississippi. In the pine-hardwood forest, 98 percent of the acid deposition was neutralized, 50 percent in the forest canopy, and 48 percent in the forest floor. In the pine forest, 75 percent of the acid deposition was neutralized, all in the forest floor. The pine-hardwood ecosystem accumulated sulfate, nitrate, and ammonia ions, and lost base cations. During seasons of deficient precipitation, dry deposition appeared to enrich the concentrations of hydrogen, nitrate, sulfate, and ammonia ions in throughfall samples at both locations. 相似文献
128.
John B. Erdmann Heinz G. Stefan Patrick L. Brezonik 《Journal of the American Water Resources Association》1994,30(6):1043-1053
ABSTRACT: Suspended solids and ammonium concentration profiles measured at five locations in Duluth-Superior Harbor during July-October 1985 were analyzed to quantify wind and ship effects on sediment resuspension and resulting harbor water quality. Wind components from the SE quadrant correlated strongly with depth-averaged suspended solids concentrations that were unaffected by ship passage or thermal stratification. Winds from that quadrant have the largest fetch in the harbor. The highest correlation (r2= 0.93) was with the 6-hour average of the ESE wind velocity component. Multiple linear regression analysis of data from post-ship passage concentration profiles yielded numerical estimates of settling velocities of 0.08 to 0.25 cm s?1, typical of ship-resuspended sediments, and vertical eddy diffusivities of 4 to 13 cm2 s1. The results suggest that ambient vertical eddy diffusivities in the harbor are less than 4 cm2 s?1 in the absence of ship passages and with winds less than 5 m s?1 (10 knots). 相似文献
129.
Peter M. Allen Jeffrey C. Arnold Bruce W Byars 《Journal of the American Water Resources Association》1994,30(4):663-671
ABSTRACT: There is considerable potential for use of channel dimension data in planning-level models for resource and impact assessment. The channel dimension data is used to route flows and sediment through the basin. The cost of obtaining actual surveyed data for large watersheds is typically prohibitive. Predictive equations have been developed based on 674 stations from watersheds across the United States which encompass a wide variety of channel types and sizes. These equations were tested against an independent data set and found to be adequate for use in planning-level models. Future research is advocated which would include data from regions and stream types not included in this study. 相似文献
130.
J. V. Brahana E. F. Hollyday 《Journal of the American Water Resources Association》1988,24(3):577-580
ABSTRACT: The method of identifying dry stream reaches in carbonate terrane as surface indicators of potential ground-water reservoirs offers a valuable exploration technique that is more rapid and less expensive than traditional exploration methods involving random test drilling. In areas where dry stream reaches occur, subsurface drainage successfully competes with surface drainage, and sheet-like dissolution openings have developed parallel to bedding creating the ground-water reservoir. The occurrence and hydraulic characteristics of such reservoirs are highly variable, as attested to by the wide range of well yields. Union Hollow in south-central Tennessee is the setting for a case study that illustrates the application of the dry stream reach technique. In this technique, dry stream reach identification is based on two types of readily acquired information: (1) remotely sensed black and white infrared aerial photography; and (2) surface reconnaissance of stream channel characteristics. Test drilling in Union Hollow subsequent to identification of the dry reach proved that a localized ground-water reservoir was present. 相似文献